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Superconducting tapes are widely used in application where large
lengths of materials are required to meet the high-power performance
and stringent weight and size requirements. Silver-clad tapes of
BPSCCO-2223 material can be produced from polyphase powders, which
reactively sinter in suit to form the BPSCCO-2223. Optimum annealing
temperatures and unique thermomechanical methods are necessary to
achieve the highest critical current density in the tapes. Reactive
sintering of polyphase tapes is extremely sensitive to annealing
temperature. There is a narrow range of annealing temperature, and
the optimum annealing temperature must be used to allow maximum
transformation without decomposition of the 2223 phase.
Continued intermittent processing after initial grain-growth annealing
is necessary to advance the chemical reaction and to promote grain
texturing. The highest current density has been seen in BPSCCO tapes
made from polyphase powder annealed for 350 h at 845℃ with three
intermittent pressing cycles. Continued thermomechanical processing
leads to a remarkable increase in current density as a result of
improved grain texturing. Completion of the annealing process between
830 and 853℃ indicates that maximum transformation of 2212 to 2223
due to endothermic reaction takes place over this narrow temperature
range. A suitable number of thermomechanical cycles and intermediate
annealing times with minimum deformation are essential to achieve
high current density.
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